纳米LiMn2O4的制备-矿冶工程.PDF

25 1 矿　冶　工　程 Vol.25 №1 2005 02 MINING AND METALLURGICAL ENGINEERING Februar 2005 LiMn O 2 4 1, 2 2 2 1 俞泽民 , 岳红彦, 郭英奎, 赵连城 (1. , 150001;2. , 150040) 　:、, , -, LiMn O 。 DTA-TG , XRD , SEM 2 4 , -。 , 300 ℃ LiMn O ;300 ℃;; 2 4 , 30 nm ;3.498 。 :;;LiMn O 2 4 :TM912.9 :A :0253-6099 (2005)01-0072-03 Preparation of Nano-LiMn O 2 4 1, 2 2 2 1 YU Ze-min , YUE Hong-an , GUO Ying-kui , ZHAO Lian-cheng (1.The School of Material Science and Eng ineering , Harbin I nstitute of Technology , Harbin 150001, Heilongj iang , China ; 2.School of Material Science and E ngineering , Harbin University of S cience and Technology , Harbin 150040, Helongj iang , China ) Abstract :Nano-LiMn2 O4 spinel oxides has been prepared successfull b roasting precursor in the air atmosphere, while pre- cursor was obtained b sol-gel techniques, with lithium nitrate and manganese nitrate as original material and citric acid as complexant.The thermal decomposition behavior of the precursor has been examined with the method of DTA-TG.The struc- ture and purit of LiMn O powder have been anal zed b means of XRD.The morpholog of it also has been observed and 2 4 grain size has been measured b SEM .The mean valenc of manganese in LiMn O has been determined b redox titration 2 4 met