等离子体发射检测器在检测高纯氦气中微量氖气的应用-LDetek.PDF

第25 卷，第 1 期 化学分析计量 Vol. 25 ，No.1 78 2016 年 1 月 CHEMICAL ANALYSIS AND METERAGE Jan. 2016 doi ：10.3969／j.issn.1008–6145.2016.01.023 等离子体发射检测器在检测高纯氦气中 微量氖气的应用* 胡树国，张体强 ( 中国计量科学研究院，北京 100029) 摘要 采用等离子发射检测器(PED) 和氦离子放电检测器(DID) 对重量法制备的氦气中微量氖气进行了检测， 对比了微量氖气在两种检测器上的灵敏度和重复性。结果显示，PED 对氖气的检测灵敏度较高，氖气含量在0.03～0.3 2 r n μmol ／mol 范围与响应值呈良好的线性关系，= 1.000 ，检测限小于1 nmol ／mol ，测定结果的相对偏差小于2%( =6) 。 利用大气压离子质谱仪对检测限测试结果进行了验证。采用等离子发射检测器检测氦气中微量氖气的方法，可以降 低微量氖气标准物质的定值不确定度，为研制高准确度微量氖气标准物质奠定基础。 关键词 等离子发射检测器；高纯氦气；微量氖气；检测限；气体标准物质 中图分类号：O657.3 文献标识码：A 文章编号：1008–6145(2016)01–0078–03 Application of Plasma Emission Detector in Determination of Trace Neon in High Purity Helium Hu Shuguo, Zhang Tiqiang (National Institute of Metrology, Bej ing 100029, China) Abstract Trace neon in helium prepared by gravimetric method was determined by gas chromatography with plasma emission detector and discharge ionization detector. Sensitivity and repeatability of trace neon in different detector were compared. The results showed that the detection sensitivity of PED was higher, the linear range of neon was 0.03–0.3 2 μmol ／mol ，the correlation coefficients (r ) was 1.000 ，the detection limit was less than 1 nmol ／mol ，the RSD was less n than 2%( =6). By comparing the data of atmosphere pressure ion mass spectrometry ，the reliability of the results was verified. The determination of trace neon in