磺化杂环共聚醚砜复合纳滤膜的制备与性能-高分子材料专业论文.docxVIP

磺化杂环共聚醚砜复合纳滤膜的制备与性能纳滤膜均表现出优异的耐化学稳定性及耐氧化性，其中SPPBES．LiCl复合纳滤膜性能变 磺化杂环共聚醚砜复合纳滤膜的制备与性能 纳滤膜均表现出优异的耐化学稳定性及耐氧化性，其中SPPBES．LiCl复合纳滤膜性能变 化最小。 关键词：磺化杂萘联苯共聚醚砜；复合膜；纳滤膜；热稳定性；耐氧化性 万方数据 大连理工大学硕士学位论文Preparation 大连理工大学硕士学位论文 Preparation and properties of SPPBES composite nanofiltration membranes Abstract Copoly(phthalazinone biphenyl ether sulfone)(PPBES)is a kind of thermoplastic functional materials with perfect mechanical strength，temperature resistance and film forming properties． Accordingly， sulfonated copoly(phthalazinone biphenyl ether sulfone)(SPPBES)is a good choice for being functional layer material of composite nanofiltration membrane，which Can improve the hydrophilicity as well as optimizing comprehensive performance of the material． In this work，two kinds of sulfonated copoly(phthalazinone biphenyl ether sulfone)(SPPBES) compoise nanofiltration membranes were prepared with copoly(phthalazinone biphenyl ether sulfone)(PPBES)and polyether sulfone(PES)as ultrafiltration support membranes，respectively．The influence of conditions on the structure and performance of composite nanofiltration membrane were studied，including sulfonated degree，polymer concentration,heat treatment time and temperature．It was found that the salt removing rate increased and the water flux decreased with the increasing of polymer concentration，heating time and heming temperature．The composite nanofiltration membrane achieved good comprehensive performance，which Was prepared from SPPBES with sulfonated degree of 0．9 and heated for 0．5 h at 90℃． The morphology，hydrophiticity and surface chemical composition of the composite nanofiltration membrane were investigated by scanning electron microscope，static contact angle measurement and infrared total reflection．The oxidation stability was studied by free chlorine immersion method．The effects of operating temperature and pressure on the perforinance of composite nanofitration membrane were investigated．When the operating pressure increased from 0．4 MPa to