磺化聚苯醚介孔氧化硅杂化膜的制备及性能研究-化学工程专业论文.docxVIP

AbstractAb Abstract Ab stract Compared with the single component of organic membrane and inorganic membrane，organic-inorganic hybrid membrane which prepared by mixing mesoporous silica and organic polymer，combined the advantages of inorganic materials and organic polymer,and possessed good flexibility,thermal stability, chemical stability and mechanical strength．In this paper，the mesoporous silica(MS) with a certain morphology was synthesized successfully,and mixed with sulfonated poly(2，6-dimethyl-1，4。phenyleneoxide)(SPPO)for preparing organic．inorganic hybrid membranes via solution blending method．Diffusion dialysis experiment of NaOH／Na2W04 system has been carried out for alkali recovery to detect the separation property of as-prepared membranes．Effects of loading content of mesoporous silica on mechanical and thermal stability,micro-morphology and separation properties of hybrid membranes have been studied．The research will be spread from the following two aspects： Content of the fh-st section was preparation and properties of sodium type sulfonated poly(2，6-dimethyl-1，4-phenyleneoxide)／amino-modified mesoporous silica (Na-SPPO／AMMS)hybrid membranes．Firstly，amino-modified mesoporous silica (AMMS)was synthesized via template method and sol-gel process．transmission electron microscopy images(TEM)and N2 adsorption-desorption curve results showed that the synthetic AMMS has a uniform pore size and highly ordered pores， pore size at about 5．5nm．Na-SPPO／AMMS hybrid membranes were prepared by solution blending method and the loading content AMMS was 0，2％，4％，6％，8％ (mass ratio to Na-SPPO)．The water upmke(WR)，ion exchange capacity,alkali resistance，mechanical strength，thermal stability and microstructure of as-prepared membranes were tested．The results indicated that the membrane water content between 1 36．4％-1 93．6％，ion exchange capacity between 2．1 3·2．32mmol。swelling degree between 1 14．9％-1 86．2％，mass loss rate between 1 7．1％．25．8％，tensile strength(TS)betwe