核壳型短链含氟丙烯酸酯乳液的合成及表征.docxVIP

核壳型短链含氟丙烯酸酯乳液的合成及表征 敏，张跃军*唐( 南京理工大 核壳型短链含氟丙烯酸酯乳液的合成及表征 敏，张跃军* 唐 ( 南京理工大学 化学化工学院，江苏 南京 210094) 摘要: 该文研究了核壳型短链含氟丙烯酸酯乳液的合成与表征。以甲基丙烯酸甲酯( MMA) 和丙烯酸丁酯( BA) 的共聚体为核，短氟碳链 2-( 全氟己基) 乙基甲基丙烯酸酯 ( FMA6 ) 和非氟烷基丙烯酸酯的共聚体为壳，采用多 步乳液聚合法，合成系列具有核壳结构的含氟丙烯酸酯乳液，研究了壳相中氟单体用量和非氟烷基丙烯酸酯的 烷基链长度 n( 链长 n = 4、8、12、16、18) 对产物疏水疏油性能的影响，并对产物进行表征。结果表明: 当采用氟单 体用量为总单体质量的 8. 5% ，甲基丙烯酸十六酯( CMA) 的共聚体为壳层时，由合成乳液制得的乳胶膜的疏水 疏油性最佳，对水接触角为 124. 67° ，对二碘甲烷接触角为 112. 76° 。FTIＲ、TEM 和 DSC / TGA 表征表明，原料单 体均参加了反应; 乳液颗粒具有明显的核壳结构; 聚合物存在两个玻璃化温度( － 18. 87 ℃ 和 32. 08 ℃ ) ，热分解 温度比不含氟的聚合物提高了近 20 ℃ 。由此说明，用合成的核壳型短链含氟丙烯酸酯乳液制得的涂膜具有优 异的疏水疏油性和耐热性能。 关键词: 核壳结构; 短氟碳链; 疏水疏油; 乳液聚合; 丙烯酸系列化学品 中图分类号: TS195． 2; TQ316． 334 文献标识码: A 文章编号: 1003 － 5214( 2014) 09 － 1115 － 06 Synthesis and Characterization of Short-Chain Fluorinated Acrylate Emulsion with Core-Shell Structure TANG Min，ZHANG Yue-jun* ( College of Chemistry and Chemical Engineering，Nanjing University of Science and Technology，Nanjing 210094， Jiangsu，China) Abstract: The synthesis and characterization of an emulsion of core-shell structure and containing short-chain fluorinated acrylate were studied in this paper． A series of emulsions of core-shell structure and containing fluorinated acrylate copolymer in shell was synthesized via a multi-step seed emulsion polymerization，and meanwhile，by using the copolymer of methyl meth acrylate ( MMA ) with butyl acrylate( BA) as the core and the copolymer of 2-( perfluorinated hexyl) ethyl methacrylate ( FMA6 ) with acrylate linking n-alkyl chain of various length( n = 4，8，12，16 and 18，respectively) as the shell． The effects of both the content of the fluorinated monomers and the length of n-alkyl chain of acrylate in the shell on oil and waterproof performance were especially investigated，based on a systematical optimization of process conditions． The obtained products were then characterized and analyzed． The results show that the emulsion with w( FMA6) = 8. 5% and methyl hexadecyl methacryl