西北师大光催化系化合物1.pptVIP

Working Report Preliminary WorK Reading Literature Next Plan Preparation of BiOCl XRD FT-IR SEM UV-vis DRS Degradation Cycling test Reaction mechanism Literature Review Next Plan 1. BiOCl 2. BiVO4 and BiPO4 Reporter: Hui Juan Mentors: Professor Wang Date: 2012.11.24 Bi2O3 HCl BiCl3-HCl pH=2 NH3.H2O White BiOCl △ , 40℃ Fig.1. The XRD patterns of BiOCl Fig.2. FT-IR spectrum of BiOCl Fig.3. SEM of the BiOCl Fig.4. UV-vis DRS spectra of BiOCl Fig.5. the degradation of different dyes in UV light Fig.6. the degradation of different dyes in visible light Fig.5. the cycling test about degradation of RhB in UV light e- e- e- e- h+ h+ h+ h h+ VB CB BiOCl Visible light RhB products Fig.9. The schematic of reaction mechanism UV light RhB* RhB e- e- e- RhB*. × BiOCl O2 O2- . Scheme 1 Illustration of formation mechanism of BiOI SCNs: (a)original formation process; (b) simulation formation process. Ling Zan et al. J. Mater. Chem., 2011, 21, 12479–12484 Fig. 1. SEM images of the annealing products from BiI3. (a)BiI3; (b)350 ℃, 10 min; (c)350 ℃, 1 h; (d)350 ℃, 3h; (e)350 ℃ , 5h;(f) 450 ℃, 3h. Fig. 3 . (a) FESEM image of BiOI SCN-4; (b) FESEM of irregular BiOI; (c) the thickness of BiOI SCN-4; (d) the thickness of BiOI SCN-6; Fig. 4. The percentage removal of RhB with irregular BiOI BiOI SCN-4and BiOI SCN-6 under visible light irradiation.