环氧树脂增韧机理的研究-高分子化学与物理专业论文.docxVIP

复旦大学硕士学位论文 复旦大学硕士学位论文 摘要 摘 要 本论文对环氧树脂增韧机理进行了较深入的探讨。 为了定量考察“海岛”结构对增韧的贡献，本论文合成了不同分子量的端 羟基聚酯，优选了三个样品，使得改性体系出现均相、临界相分离和部分相分离 三种状态。研究结果区分了均相部分和相分离部分对增韧的贡献，结果证实“海 岛”结构对增韧有重要贡献，在我们所研究的体系中，“海岛”结构的增韧贡献 大约是均相部分增韧贡献的3一倍，通过预反应加强化学键合能提高增韧效果， 以往文献对“海岛”结构增韧机理的解释是合理的。 为了定量比较交联密度和链段的柔顺性对增韧的影响，本论文合成了不同 碳原子数的直链二元酸聚酐固化剂，设计了5种等交联密度，不同链段柔顺性的 固化体系。结果表明交联密度对固化体系的玻璃化温度的影响是决定性的，链段 的柔顺性影响不大。交联密度对固化体系的韧性影响也是主要的。研究链段柔顺 性对韧性的影响得到一个有趣的结果：交联网络中短链段固化剂的含量对韧性起 主导作用，长链二元酸聚酐的柔顺性增加对韧性影响不大。这一推论还有待于进 一步的实验验证，本论文在这方面的工作尚未全部完成。 复旦大学硕士学位论文 复旦大学硕士学位论文 英文摘要 Abstract Toughening mechanism of epoxy resins has been investigated in a certain depth in this paper．In order to study the effect of‘‘domain’structure on toughening mechanism quantitatively we synthesized a series of hydroxyl—terminated polyesters with different molecdar weight．We selected 3 optimized polyesters to modify epoxy resin SO that we could obtain single phase，critical phase separation and partial phase separation structure．The results distinguished the different contribution from polyester incorporated into network and phase。separated polyester and proved that phase—separated polyester Was the major factor impacting toughening effect．In OUr epoxy-polyester system，the toughening effect of‘‘domain’’polyester structure Was about 3-4 times that of polyester incorporated into network．Intensifying chemical bonding by pre-reaction could inaease the toughening effect．This paper supported the previous references interpreting the toughening mechanism of“domain’structure． In order to compare the toughening effect of crosslinking density and chain fle对bility on toughening effect，we synthesized a series of aliphatic poly anhydrides using different aliphatic diacids．We devised 5 curing systems with the salne crosslinking density but with different chain flexibility．The results showed that crosslinking density was the major factor determining the glass transition mmpemture， while the chain flexibility had little influence on TB．Crosslinking density was also t