高分子材料论文.docVIP

PAGE PAGE 1 本科毕业论文 (设计) 题 目：_无皂乳液聚合法合成单分散聚苯乙烯微球的研究_ 学 院：___化学化工与环境学院___ 专 业：____高分子材料与工程____ 姓 名：_________刘__凯_________ 指导教师：________李洪亮_________ 2007 年 5 月 25 日 无皂乳液聚合法合成单分散聚苯乙烯微球的研究 摘 要 近年来，为了克服由于加入乳化剂而带来的弊端(例如:乳化剂的使用对环境造成污染，产品中的乳化剂影响产品的电性能，光学性能，表面性能及耐水性能等)，人们正在致力于开发无皂乳液聚合技术——无皂乳液聚合即聚合反应过程中无乳化剂或仅含少量乳化剂(浓度小于CMC)的乳液聚合。目前大多数采用的制备方法是:1、在反应体系中加入阴离子型功能单体参与共聚，以改善无皂乳液在聚合速率慢、稳定性差、产品固含量低等方面的不足；2、阳离子性功能单体参与共聚，阳离子胶乳粒子对污水中各种带负电荷微粒有很强的结合能力，在污水处理方面有独特的作用，在造纸工业中也有广泛的运用。 本文综述了无皂乳液聚合的理论进展、无皂胶乳的制备、聚合工艺进展、以及无皂胶乳的应用等。 关键词:无皂乳液聚合；苯乙烯；微球；单分散性 ABSTRACT Recently, in order to overcome the disadvantage of emulsifier (for example: the utilization of emulsifier will bring pollution to the environment, the emulsifier in a product has some injurious in effect on the electrical, optical or water-resistant performance and surface properties), the development of the soap-free emulsion polymerization-the process with no emulsifier or only trace emulsifier (concentrationCMC) in the reaction system has been paid much more attention. The preparation method which has been used mostly is: charging an anionic comonomer into the soap-free emulsion polymerization system for the purpose of improving the disadvantage in the slow rate of polymerization, weak stability, and low solid content. Secondly, charging a cationic comonomer into the soap-free emulsion polymerization system. The cationic latex particles play an important role in sewage disposal combining with anionic particles easily, and the cationic latex particles also have been used widely in papermaking. The methods to prepare function polymer microballs by soap-free emulsion polymerization, progress in soap-free emulsion polymerization technologies, as well as application of emulsion are reviwed. KEYWORDS soap-free emulsion polymerization；styrene；microsphere；monodispersity 目 录 前言……………………………………………………………………………………… 正文……………………………………………………………………………………… 1.综述部分…………………………………………………………………………… 1.1 无皂乳液聚合定义及特点…………………………………………………… 1.2