微波等离子体炬原子发射光谱法测定米粉中微量元素-大学化学.PDF

大学化学(Daxue Huaxue) September Univ. Chem. 2017, 32 (9), 41－45 41 ∙化学实验∙ doi: 10.3866/PKU.DXHX201704019 微波等离子体炬原子发射光谱法测定米粉中微量元素 ——一个大学化学仪器分析实验的设计与实践 冯国栋 宋志光* 郭玉鹏 (吉林大学化学学院，长春130012) 摘要：设计了一个科研参与型的大学化学仪器分析实验。本实验应用MPT 原子发射光谱仪对米粉中的 金属元素(Ca，Cu，Fe，Mn)进行了检测分析。对影响金属元素检测性能的实验条件，如微波等离子体 炬的微波功率和维持气流量进行了系统的考查及优化。最后，通过对样品进行测定，证实与标准含量相 符，结果比较满意。学生在实验过程中，可以学习和掌握样品的前处理方法、原子发射光谱的机理和仪 器测试条件的优化。 关键词：微波等离子体炬；原子发射光谱；米粉；微量元素 中图分类号：G64 ；O6 Determination of Trace Elements in Rice Flour Using Microwave Plasma Torch-Atomic Emission Spectrometry: Design and Practice of a College Chemistry Experiment of Instrumental Analysis * FENG Guo-Dong SONG Zhi-Guang Guo Yu-Peng (College of Chemistry, Jilin University, Changchun 130012, P. R. China) Abstract: A research type experiment of instrumental analysis was designed for undergraduates. In this experiment, microwave plasma torch-atomic emission spectrometer (MPT-AES) was used to detect trace metal elements (Ca, Cu, Fe and Mn) in flour samples. The experimental conditions, such as microwave power and supporting gas flow rate were optimized. Finally, the standard rice flour sample was detected under the optimum experimental conditions with a satisfying result. During this experiment students can learn and master the sample pretreatment method, the mechanism of atomic emission spectrum and optimization of the equipment testing. Key Words: Microwave plasma torch; Atomic emission spectrometry; Rice flour; Trace elements 粮食是人们生活的必需品，其主要成分为碳水化合物，但在其生长过程中会从环境中吸附一定量