环氧酸化碳纳米管玻纤微纳复合材料的制备工艺及性能-化学工程专业论文.docxVIP

ABSTRACTPolymer based composite materials have the advantages of light weight, high strength, good temperature resistance, good corrosion resistance, high fatigue and they are widely used in military field and private economy industry. However, traditional micron filler such as glass fiber exhibit good processing ability but enhance the matrix limitedly in the micron level; while the novel nanofillers such as carbon nanotubes can strengthen the matrix resin more effectively in the nanometer level but they are easy to agglomerate, difficult to disperse and be processed. Therefore, this thesis chooses epoxy resin as polymer matrix, the glass fiber for micron sized fillers and carbon nanotubes as nanofillers. This paper aims to study the preparation and properties of epoxy/carbon nanotubes/glass fiber micro-nano composite material.First, the acidified carbon nanotubes were modified and characterized to reduce the nature agglomeration of carbon nanotubes and achieve good dispersion for the preparation of epoxy/acidified carbon nanotube/glass micro-nano composite materials. And then the effects of carbon nanotubes on the curing behavior of epoxy resin were studied and the curing process parameters and processing parameters of micro-nano composite material were offered.Second, epoxy/acidified carbon nanotubes/glass micro-nano composite was prepared by the wet process and the dry process. The mechanical properties of the nano composite evaluation, microstructure and thermal properties changed with the content of carbon nanotubes. Found that the mechanical properties two process with the content of the acidified carbon nanotube increases first, then decreases, the acidified carbon nanotubes to mechanical properties of 6wt% optimal. The thermal properties of composites with carbon nanotube content of acidification increase one time increases, reaches a maximum in the acidified carbon nanotubes reached 10wt%.Finally, from the process, properties of composite materials, the