山苍籽核仁油合成生物柴油研究-中南大学学报.PDF

40 6 () Vol.40 No.6 2009 12 Journal of Central South University (Science and Technology) Dec. 2009 ( 410083) −SO42−/ZrO2 (CTMAB)/NaOH SO42−/ZrO2 4% SO 2−/ZrO 10׃168 4 h2.52 mg/g 4 2 25 0.5%1%NaOH 6׃115 min 97.6% TQ645.5 A 1672−7207(2009)06−1517−05 Preparation of biodiesel from litsea cubeba kernel oil CAI Hai-qing, ZHONG Shi-an, AI Hai-dong (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) Abstract: The production technology of biodiesel from litsea cubeba kernel oil with solid acid−esterification and phase transfer catalyst−transesterification was studied. First, litsea cubeba kernel oil was esterified with methanol catalyzed by solid acids SO 2−/ZrO , and then the first reaction product was transesterified with methanol catalyzed by the phase 4 2 transfer catalyst of hexadecyl-trimethyl-ammonium bromide (CTMAB)/NaOH. The results show that the optimal parameters of esterification are as follows: 4% of SO 2−/ZrO , molar ratio of methanol to litsea cubeba kernel oil 10׃1, 68 4 2 of reaction temperature and 4 h of reaction time, the acid value decreases to 2.52 mg/g. Compared with the traditional acidic-catalyzed method, this method has the advantages of no acid proof equipment, easy to recycle catalyst and no acidic waste water emission. The optimal parameters of transesterifi