低弹性吸震发泡材料硫化交联温度及其力学性能的研究.pdf

33 3 ( ) Vol. 33 No. 3 2005 6 Journal of Fuzhou University(Natural Science) Jun. 2005 : 1000- 2243(2005) 03- 0332- 07 (, 350007) : - (SIBC) ( BIIR) , (TA) , (SIBC/ BIIR) . , (DCP) (AD) , , 12% . , . 433~ 443 K, 438K. ( CRI) . (SEM) . : ; ; ; ; : TQ334.2 : A Studyonpropertyandcuring temperatureof lowelasticity shock- absorbing blowing material IU Can- pei (College of Chemistry and Materials, Fujian Normal University, Fuzhou, Fujian 350007, China) Abstract: A polymer blend ( SIBC/ BIIR) was prepared by melt blending styrene- isoprene block copo lymer ( SIBC) and bromobutyl rubber ( BIIR) filled with inorganic filler talc (TA) . SIBC/ BIIR was cross- linked with a cross- linking agent of dicumyl peroxide ( DCP) and blown with a blowing agent of azodicarbonamide (AD) under the certain conditions of pressure and temperature to form a closed- cell low elasticity shock- absorbing blowing cross- linking material, which has excellent shock- absorbing performance, no higher than 12% of elasticity and excellent mechanical properties. The effect of the blend ratio and curing temperature on mechanical properties of this material was studied and the curing behavior of this blend system was also investigated by using a torque rheometer. The results show that a better curing temperature range is 433~ 443K and the optimum temperature is at 438K. It was suggest ed that curing rate index ( C RI) is a referenced technical index for determining the curing temp