毕业论文桌面(煤焦共气化).docx

PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT28 煤焦与H2O/CO2在气化过中碱金属和碱土金属的迁移规律 摘 要 本研究选取富含AAEMs的五彩湾煤为研究对象，通过逐级提取法考察了五彩湾煤焦中AAEMs的存在形式。制备了800 °C下一系列不同碳转化率的气化残焦，通过原子吸收光谱研究了CO2、H2O和H2O/CO2气氛下气化过程中AAEMs含量的变化趋势，通过N2吸附测试观察了原煤焦及气化残焦的孔结构。发现五彩湾煤焦中的Na和K大部分是以水溶态形式存在，而Ca主要以可交换离子态形式存在。煤焦在H2O气氛下比在CO2气氛下的孔的总体积大。 关键词：五彩湾煤，气化残焦，赋存形态，形式 Alkali metal and alkaline earth metal migration patterns in the gasification of Coal tar and H2O/CO2 ABSTRACT This study selected wucaiwan coal as the research object, through the extraction step by step to investigate the existence form of AAEMs in wucaiwan coal .Preparation for a series of different carbon conversion rate under 800 gasification residual coke, was studied by atomic absorption spectrum of CO2, H2O, and H2O/CO2 atmosphere AAEMs content change trend of the gasification process,and The original coal tar by N2 adsorption test observation and gasification residual pore structure of coke. Found that most Na and K of the wucaiwan coal is in the form of water soluble state, and Ca mainly exists in the form of exchangeable ions state. Under CO2 atmosphere, Ca would happen to be the sintering of carbonate and under water atmosphere won’t. KEY WORDS: wucaiwan coal，sodium; pyrolysis，existence form，transformation 目录 摘要………….……………………………………………………………….I ABSTRACT …………………..……..………………………………………II TOC \o 1-3 \h \z \u HYPERLINK \l _Toc453767324 第一章 绪论 PAGEREF _Toc453767324 \h 1 HYPERLINK \l _Toc453767325 1.1课题的研究背景及意义 PAGEREF _Toc453767325 \h 1 HYPERLINK \l _Toc453767326 1.1.2煤炭品种分布 PAGEREF _Toc453767326 \h 2 HYPERLINK \l _Toc453767327 1.1.3 现代煤炭问题 PAGEREF _Toc453767327 \h 2 HYPERLINK \l _Toc453767328 1.2 煤气化 PAGEREF _Toc453767328 \h 3 HYPERLINK \l _Toc453767329 1.2.1 煤气化技术的选择及应用 PAGEREF _Toc453767329 \h 3 HYPERLINK \l _Toc453767330 1.2.2 煤热解化学反应 PAGEREF _Toc453767330 \h 4 HYPERLINK \l _Toc453767331 1.2.3 煤的气化反应 PAGEREF _Toc453767331 \h 4 HYPERLINK \l _Toc453767332 1.3 AAEMs在煤热解中的迁移 PAGEREF _Toc453767332 \h 6 HYPERLINK \l _Toc45376733