氰乙基己二胺化合物合成及其组成分析.pdf

氰乙基己二胺化合物合成及其组成分析 赵飞明 ( ) 　航天材料及工艺研究所 　北京 　100076 　 汪树军 ( ) 　北京石油大学化工学院　北京 　102200 　 ( ) ( ) ( ) 文 　摘 　用丙烯睛和己二胺可合成环氧树脂固化剂 。借助核磁共振 NMR 、红外光谱 IR 、质谱 MS ( ) ( ) 分析该固化剂组成 。结果表明:当己二胺 HMD 、丙烯睛 AN 按摩尔比为 1 ∶1 反应时 ,除主要产物氰乙基己 二胺外 ,产物中同时存在二氰乙基己二胺 。 关键词 　固化剂 ,合成 ,核磁共振 ,红外光谱 ,质谱 Synthesis and Analysis of Cyanoethyl Hexamethylenediamine Zhao Feiming ( ) 　Aerospace Research Institute of Materials and Processing Technology 　Beijing 　100076 　 Wang Shuj un ( ) 　Institute of Chemical Engineering ,Beijing University of Petrolium 　Beijing 　102200 　 Abstract 　The curing agent for epoxy is synthesized by reacting hexamethylenediamine with acrylonitrile . Synthesis method has been improved . The compositions of the curing agent are analyzed with infrared spectroscopy ,mass spec troscopy and nuclear magnetic resonance . It is found that when the reaction between hexamethylenediamine and acryloni trile is carried out in the mole ratio of 1 ∶1 ,main product of the monocyanoethylation hexamethylenediamine and byprod uct of the bicyanoethylation he