海卤水提锂新技术研究现状及展望.pdf

第 31 卷第 3 期 高 校 化 学 工 程 学 报 No.3 Vol.31 2017 年 6 月 Journal of Chemical Engineering of Chinese Universities June 2017 文章编号：1003-9015(2017)03-0497-12 海卤水提锂新技术研究现状及展望  赵晓昱 （天津科技大学化工与材料学院 天津市海洋资源与化学重点实验室, 天津 300457 ） 摘 要：采用 HistCite 统计分析 Web of Science 数据库中 1998 年以来所有关于海水或者盐湖卤水提锂技术的研究，对区 别于现有传统溶液提锂的新技术进行综述，并按照电化学法、离子筛吸附、离子液体萃取、纳滤+渗析、膜结晶的分 类分别介绍国际最新研究进展。近些年纳米材料和新型储能概念的快速发展是溶液提锂新技术研究得以突飞猛进的直 接推动力，将来这些新技术实现产业化应用的关键则是如何基于这些新材料和新技术，结合各地海卤水特有真实组成 和气候条件，开展适合当地海卤水体系的工艺设计，设备优化，参数优化等过程研究。 关键词：海卤水提锂；电化学法；离子液体；纳滤；膜结晶 中图分类号：TQ115 文献标识码：A DOI ：10.3969/j.issn.1003-9015.2017.03.001   Review on New Techniques for Lithium Extraction from Seawater and Brine ZHAO Xiao-yu (Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science Technology, Tianjin 300457, China) Abstract: References from Web of Science about lithium extraction from seawater and brine were statistically analyzed and new techniques with a category of electrochemical extraction, ion sieve, ionic liquid extraction, nanofiltration+dialysis and membrane crystallization were discussed in detail. It can be found from literature that the development of lithium extraction from solutions is driven by the fast growth of nanomaterials and novel energy storage techniques.The key for industrialization of these new techniques is how to customize and optimize those processes based on different chemical compositions of local seawater/brine and also weather conditions. Key words: lithium extraction; seawater and brine; electrochemical; ionic liquid; na