甲基丙烯酸和对苯乙烯磺酸钠共聚反应动力学研究.pdfVIP

29 2 Vol. 29, No . 2 2008 6 Journal of Hebei University of Science and T echnolo y June 2008 : 1008- 1542( 2008) 02-0133- 04 曹丽娜, 罗青枝, 肖丽彬, 窦海洋, 王德松 ( 河北科技大学理学院, 河北石家庄 050018) : 以过硫酸钾-亚硫酸氢钠为引发剂, 研究了甲基丙烯酸和 苯乙烯磺酸钠水溶液自由基共 聚合反应采用膨胀计法得到共聚反应速率, 考察了引发剂浓度单体浓度反应温度 共聚反应 速率的影响结果表明, 随着引发剂浓度单体浓度和反应温度的提高, 共聚反应速率增大建立 了共聚反应动力学关系式, 测得共聚反应表观活化能为58. 97 kJ/ mol : 甲基丙烯酸; 苯乙烯磺酸钠; 共聚; 聚合动力学 : O631. 5 : A Study on copolymerization kinetics of methylacrylic acid and sodium p- styrene sulfonate CAO L-i na, LU O Qin -zhi, XIAO Li-bin, DOU Ha-i yan , WAN G De-son ( Colle e of Sciences, H ebei University of Science and T echnolo y , Shijiazhuan H ebei 050018, China) Abstract: The water solution radical copolymerization of methylacrylic acid and sodium p-styrene sulfonate is studied w ith po- tassium persulfate and sodium bisulfite as the initiator. T he effects of monomer concent rations, initiator concentrations and re- action t em perat ures on copolymerization rates, determined by t he dilatometer method, are inspected, and the results indicate that the copolymerization rates increase w ith t he incretement of monomer concent rations, init iator concentrations and reaction temperatures. The copolymerizat ion dynam ic relat ionship is obtained, and the apparent activat ion ener y is 58. 97 kJ/ mol. Key words: met hylacrylic acid; sodium p-styrene sulfonate; copolymerization; kinetics of polymerization ( SSS) , , , [ 1~ 4] , , , -, ( M AA) , , , , , M AA- SSS : 2007- 11-26; : 2008- 01-08; : : () : ( 1984- ) , , , , : 134 2008 1 1. 1 ( , ) ; ( , ) ; ( , ) ; ( , ) ; ( , ) ; ( , )