镁负极加工状态与缓蚀剂对镁空气电池的影响-材料科学与工程专业毕业论文.docxVIP

重庆大学硕士学位 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT Magnesium alloys, with its low density, high electrochemical activity, low standard electrode potential and high energy density, have a broad prospect in the field of chemical power source. However, the serious hydrogen evolution, voltage hysteresis and high processing cost of magnesium alloy have become a barrier of the extensive development of magnesium battery anode materials. Therefore, the electrochemical properties and discharge performance of AZ31B magnesium alloy with different processing conditions were investigated. Extruded, rolled, cast-rolled and as-cast AZ31B magnesium alloys were prepared as the anode materials. It makes the theoretical basis for the cost-effective magnesium battery anode materials. Based on the Tafel polarization curve, electrochemical impedance spectroscopy (EIS), chronopotentiometry, gravity method and electronic scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and battery discharge test, the electrochemical properties of AZ31B magnesium alloy with different processing conditions were studied. The magnesium battery was made with the magnesium anode, self-made MnO2 air cathode and the 3.5 wt.% NaCl solution. The discharge performance of magnesium air battery at 5mA·cm-2 and 10mA·cm-2, together with intermittent discharge at 5mA·cm-2 have been investigated respectively. The four kinds of inhibitors of lithium chromate dehydrate, tryptophan, hexamethylenetetramine, lanthanum acetate has been added to the magnesium air battery to study the constant and intermittent discharge performance. The results are as follows: ① In the test of electrochemical performance, the extruded magnesium alloy has negative equilibrium potential and high electrochemical activity, lower corrosion current density of 0.054 mA·cm-2 due to the finer grain size and uniform organization composition. Its corrosion resistant performance is the best; Rolled and cast-rolled magnesium anode