氯化钠在聚苯胺环氧树脂复合材料膜中的渗透研究-膜科学与技术专业毕业论文.docxVIP

ABSTRACT Polyaniline has many advantages including cost e的ctive，也.cile synthesis，redox reversibility ，and unique dopi吨 mechanism ，high chemical and environmental stability. Membranes containing polyaniline used for water and gas separation， protonexchange membrane fuel cells，metal anticorrosion and some other applications have been reported in recent years. Here，ployaniline-epoxy composite membranes were prepared，during which polyaniline with different morphologies ‘也 were used as filling materials，and epoxy resin as matrix. Scanning electronic microscopy (SEM) wωusedωcharacterize the surface and cross-section of the membranes，uv.翩V叽is S阴pe仰c臼仿.叩hotωom创ete创町r w;础 also used ωto chara倪c忧terize membra况an pol忖y即d圳lin.e w础as found 创 d伽le membranes surfacωe. The cross-section SEM image indicates 由at dispersion of polyaniline is very well and there a few aggregations. uv-Vis Spectroscopic measurements indicate that PANI.epoxy composite membranes con阳ining PANI nanoparticles and PANI nanosheets have di的rent ultraviolet spectra from composite membranes containg PANI nanowires. Chloride ion has great effect on metallic electrochemical corrosion. Here， permeation behavior of sodium chloride in PANI叩oxy composite membranes was studied. The perme副ion of sodium chloride 白rough composite membranes was recorded acωrding to the change of conductivity of solutions. Diffusion coefficients of sodium chloride in PANI epoxy composite membranes were calculated. The obtained diffusion coefficients calculated with data at t=20 hours demonstrate that the content and morphologies of PANI have significant effect on chloride ion diffusion， and were lower about one order of magnitude in PANI-epoxy composite membranes than th剧。fepoxy resi伊 membrane. h ηlis experimental results offer an optimized method to prepare polyaniline-epoxy composite membrane，and offer a novel insight in researching PANI anti corrosion coatin