煤矸石合成沸石及对氨氮废水吸附性能的研究-环境工程专业毕业论文.docxVIP

内蒙 内蒙古科技大学硕士学位论文 PAGE PAGE IV Abstract With the fast industrialization of our country, our sources are getting more and more intense and water are polluted, so it is very important to reuse the deserted sources and to treat waste water. Ammonium nitrogen waste water, if not treated well, will cause eutrophication in water body, and harm human organs. Low recyclying rate of coal gangueand water granulated slag leads to occupation of large area of precious land and pollution of the environment. The paper chooses waste coal gangue as raw materials to produce zeolite by alkali melting method to solve the problem of limited sources, hard to regenerate, high cost of nature zeolite. The other zeolite involves addition of water granulated slag to coal gangue and synthesys by alkali-ultrasonic method. The produced zeolites are used as adsorbent to treat ammonium nitrogen waste water. The subject studied the adsorption mechanism of the zeolite to ammonium nitrogen by adsorption isothermal test and kinetics tests. The adsorption ability to ammonium nitrogen of zeolite produced by alkali melting method was compared with that of produced by alkali melting-ultrasonic method, the factor affacting adsorption performance of baking time, solid-liquid ratio, aging time, crystallization time; dose of water granulated slag, ultrasonic time, solid liquid ratio, crystallization temperature, crystallization time were studied: the latter has smaller solid-to-liquid ratio and matures faster. The scanning electric mirror and XRD spectrum show that the zeolite added with slag has more fluffy form, the synthetical zeolite has better crystallinity than that without adding slag. The best condition for the synthetical coal gangue to adsorb ammonium nitrogen is: dose 0.024g/ml, vibration time 60min, pH 7; the remove ratio of ammonium nitrogen under this condition is 63.63%; the best condition for the synthetical coal gangue slag to adsorb ammonium nitrogen is: dose 0.024g/ml, vibration time 45mi