降膜结晶分离提纯对二甲苯-华东理工大学学报.PDF

DOI:10.14135/ki.1006-3080. 20180424003 降膜结晶分离提纯对二甲苯 1 1 1 2 1 王 瑞 ，许妍霞 ，宋兴福 ，吴非克 ，于建国 (1.华东理工大学国家盐湖资源综合利用工程技术研究中心，上海 200237 ； 2. 常州瑞华化工工程技术有限公司，江苏常州 213000) 摘要：降膜结晶是一种重要对二甲苯提纯方式。本文以含有 75%对二甲苯（质量分数）的混二甲苯 为原料，研究降膜结晶分离提纯对二甲苯过程，考察挂膜、进料速度、预冷温度、结晶温度、降温速率 等工艺条件对结晶过程影响，以及发汗终温、升温速率对发汗过程影响。研究结果表明，结晶条件为挂 膜、进料线性喷淋密度360.53 ml/(m·min)、预冷温度25 ℃、结晶温度15 ℃、降温速率0.15 ℃/min，以 及发汗条件为升温速率1 ℃/min、发汗终温10 ℃时，可获得纯度高于99.50%的对二甲苯产品。 关键词：对二甲苯;降膜结晶;分离提纯;工艺优化 中图分类号：TQ026.7; TQ241.1 文献标志码：A Separation and Purification of P-xylene by Falling Film Crystallization 1 1 1 2 1 WANG Rui , XU Yan-xia , SONG Xing -fu , WU Fei-ke , YU Jian-guo (1.National Engineering Research Center for Integrated Utilization of Salt Lake Resources, East China University of Science and Technology, Shanghai 200237, China; 2. Changzhou Ruihua Chemical Eng Tech Co. Ltd, Changzhou 213000, Jiangsu, China ) Abstract: Falling film crystallization is an important way to separate and purify p-xylene. At present, p-xylene is mainly produced by toluene disproportionation technology, toluene methanol alkylation technology, benzyl alcohol alkylation technology and so on. However, all of the products by these processes are the mixture containing o-xylene, m-xylene and p-xylene, and mass fraction of p-xylene is more than 70%. It is difficult to separate and get high purity p-xylene by distillation because of their close melting point. Therefore, it is necessary to deve