空间位阻效应对聚合物温敏性影响的研究-高分子化学与物理专业毕业论文.docxVIP

湘潭大学硕士学位论文 II II Abstract In recent years, thermoresponsive polymers have attracted increasing attention. Numerous papers reported the chemical factors and physical factors controling over the thermoresponsive behaviors of polymers. Less work has appeared, however, regarding steric hindrance effect on thermoresponsive behaviors of polymers. Therefore, the research of steric hindrance effect on thermoresponsive behaviors of polymers is a foresight work. This paper gave a careful description on the synthesis and characterization of two kinds of monomers and corresponding polymers. One kind of polymers was flexible polymers based on acry acid. The other was semirigid polymers based on 2-vinylterephthalic acid. The research results were declared as follows: Two kinds of new pyrrolidone-based monomers were designed and synthesized. One was based on acry acid (i.e., N-(1-meth-2-acryloyloxyethyl) pyrrolidone (M1) and N-(2-acryloyloxypropyl) pyrrolidone (M2)). The other was based on 2-vinylterephthalic acid (i.e., bis (N-(1-meth-2-hydroxyethyl) pyrrolidone) 2-vinylterephthalate (M3) and bis (N-(2-hydroxypropyl) pyrrolidone) 2-vinylterephthalate (M4)). The flexible polymers P1 and P2 were synthesized from M1 and M2 via free radical polymerization, respectively. Both P1 and P2 exhibited a thermoresponsive phase transition behavior in light water (H2O). The cloud point (CP) of P1 and P2 both decreased with increasing concentration. Yet the CP of P1 which has the stronger hindrance effect was lower than P2 at the same concentration. Well-definited semirigid polymers P3 and P4 from M1 and M2 were synthesized via RAFT polymerization, respectively. P3 and P4 exhibited the liquid crystal property, when the molecular weight reached 2.12×104 g mol-1, 1.95×104 g mol-1, respectively. The CP of P3 and P4 aqueous solution remarkably increased with increasing molecular weight. On the whole, for polymers P3 and P4 with the approximate MWs and polydisperisties, the CP of P3 which has