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染料废水处理工艺设计
摘要
本文首先论述了含染料废水处理方法的现状和进展,尤其是在化学法、生化法以及物理化学法中的新技术,其中包括膜、超声波、等离子体、超临界水氧化法(SCWO)、光催化氧化法、电化学氧化法等方法的研究现状,并对各种方法和技术进行了评价和分析。
其次,介绍了固体超强酸光催化剂的制备、光催化性能等,总结了国内外关于固体超强酸光催化剂的研究。并展望了固体超强酸催化剂的研究和应用前景。
然后,介绍了二氧化钛光催化降解活性染料废水的研究成果,对影响二氧化钛光催化降解活性染料废水的各种因素,如催化剂的形态、溶液的pH值、光源与光照强度和溶液中其它物质等,并提出了今后的发展方向。
最后,在实验中通过自制SO2-4/TiO2固体超强酸催化剂,确定了影响其光催化性能的因素,并将其应用在光催化处理染料废水中。通过改变各种实验参数,确定了处理染料废水的最佳条件,并评价和分析了SO2-4/TiO2固体超强酸催化剂对染料废水的降解能力。
结果表明:SO2-4/TiO2固体超强酸催化剂在光催化处理染料废水方面是大有发展前途的催化剂。
关键词:印染废水 固体超强酸 光催化降解 TiO2
Abstract
The present status and progress of treatment methods of waste water containing dyestuffs are reviewed firstly in the paper. The recent development of advanced techniques such as membrane, ultrasonic wave, super-critical water oxidation process (SCWO),plasma, photochemical degradation and electrochemical oxi-dation , are introduced and analyzed.
Secondly,the present situation and progress on the area of solid super acid photocatalysis were reviewed briefly,including the performance of solid super acid photocatalysis,preparation of solid super acid photocatalysts.Finally the prospects of the research and applications of super acid catalysts were predicted.
Then,the thesis summarized the development of photocatalytic degradation of reactive dyes waste water with titanium dioxide. Various factors of the catalyst of shape, pH value of the solution , the photosource , the strength and the solution other matters on photocatalytic degradation of reactive dyes waste water with titanium dioxide were investigated , and proposed the next research direction.
Finally,the factor affecting of the solid super acid’s photocatalysis functions has been ascertained in the experiment by self-restraint. The solid super acid SO2-4/TiO2 has been applied to catalyzing the dyestuff waste water. The optimum conditions treated dyestuff waste water are confirmed by the methods of experiment. And dyestuff waste water treatment effect are introduced and analyzed.
As a result, it has been found that so
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