锂离子电池复合型多孔聚合物电解质的制备及其性能研究-化工过程机械专业毕业论文.docxVIP

锂离子电池复合型多孔聚合物电解质的制备及其性能研究ScC02诱导法制备的聚合物膜为非对称膜，膜截面呈现蜂窝状的大孔结构，具有较高的 锂离子电池复合型多孔聚合物电解质的制备及其性能研究 ScC02诱导法制备的聚合物膜为非对称膜，膜截面呈现蜂窝状的大孔结构，具有较高的 孔隙率和离子电导率，然而拉伸强度偏低。随着ScC02压力升高，膜的孔隙率和离子电 导率不断增大，拉伸强度逐渐下降；而升高ScC02温度或者增加聚合物初始浓度，膜的 孔隙率和离子电导率不断下降，力学性能则逐渐增强。掺杂纳米Ti02能够同时改善膜 的电化学性能和力学性能。随着纳米Ti02粒子不断添加，膜的结晶度、孔隙率和吸液 率及拉伸强度都先升高而后下降。当纳米Ti02添加量为1％时，制备的复合多孔聚合物 电解质综合性能最佳，室温离子电导率高达3．13mS／cm，同时热稳定性较好，电化学稳 定窗口较宽，装配成Li／composite polymer electrolyte／LiC002电池，1 C放电容量可达 131．9mAh／g，循环50圈，库伦效率始终保持在99％左右。 关键词：锂离子电池；聚合物电解质；非溶剂挥发法；ScC02诱导相分离法； PVDF-HFP：PMMA：Ti02 万方数据 大连理工大学硕士学位论文Study 大连理工大学硕士学位论文 Study on the Preparation and Performances of Composite Porous Polymer Electrolyte for Lithium-ion Batteries Abstract The use of polymer electrolytes is widely regarded as a promising approach for lithium-ion batteries，due to their lack of leakage，high flexibility within the cell geometry and high physical and chemical stability．Among of all the polymer electrolytes，the composite porous polymer electrolytes(CPPEs)shows simultaneously high ionic conductivity and good mechanical strength．So the composite porous polymer electrolytes in this paper were prepared by non-solvent evaporate method and supercritical C02(ScC02)induced phase separation，respectively．The morphology，crystalline，thermal behavior，mechanical strength and electrochemical properties of these polymer membranes have been investigated by scanning electron microscopy(SEM)，X·ray diffraction pattern(XRD)，differential scanning calorimetry(DSC)，Thermogravimetric Analysis(TGA)，stess-strain test and electrochemical impedance spectroscopy(EIS)and cyclic voltammetry(cv)．Effects of the different technological parameters during preparing membranes on the structure and properties of polymer membranes were studied，aiming at obtaining GPPEs with good electrochemical and mechanical properties for practical application． First of all，the GPPEs were prepared via non-solvent evaporate method．PVDF-HFP and PMMA were polymer matrixes of membranes．DMF was solvent，and EG was