生物炭对水中五氯酚的吸附性能研究.PDFVIP

中国环境科学 2014,34(8) ：2017~2023 China Environmental Science 生物炭对水中五氯酚的吸附性能研究 * 郎印海 ,刘 伟,王 慧 ( 中国海洋大学环境科学与工程学院,海洋环境与生态教育部重点实验室, 山东 青岛 266100) 摘要：利用小麦秸秆和花生壳在 300,400,600℃条件下制备生物炭,运用元素分析仪、扫描电镜和比表面积仪对生物炭的理化性质进行表 征, 同时探讨其对水中五氯酚(PCP)的吸附特性.结果表明,随炭化温度升高,生物炭芳香性增加,极性降低.花生壳生物炭对水中 PCP 的吸附 效果优于小麦秸秆生物炭,3 种温度制备的生物炭对 PCP 吸附量表现为 400 ℃600 ℃300 ℃.随着生物炭添加量增大,水中 PCP 去除能力由 81.79%提高至 89.02%,生物炭的吸附量由 30.32 减小至 5.54mg/g.生物炭对 PCP 的吸附动力学更符合准二级动力学方程,吸附等温线符合 Freundlich 方程.吸附过程主要受快速反应控制,降低反应温度有利于生物炭对水中 PCP 的吸附. 关键词：生物炭；花生壳；小麦秸秆；五氯酚；吸附 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2014)08-2017-07 * Adsorption efficiencies of pentachlorophenol from aqueous solution onto biochars. LANG Yin-hai , LIU Wei, WANG Hui (Key Laboratory of Marine Environmental Science and Ecology, Ministry of Education, College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China). China Environmental Science, 2014,34(8)：2017~2023 Abstract ：The biochars were produced from wheat straw and peanut hull at three pyrolysis temperatures of 300, 400 and 600℃, respectively. The physico-chemical properties of biochars were characterized by elemental analyzer, scanning electron microscope and BET surface area analyzer, and the adsorption capability of biochars for the removal of pentachlorophenol (PCP) from aqueous solution was evaluated. The results showed that the aromaticity of biochars gradually increased and the polarity decreased with the increasing pyrolysis temperature. The adsorption capability of peanut hull biochars was higher than that of wheat straw biochars.