柴油萃取脱硫工艺研究.docVIP

柴油萃取脱硫工艺研究 柴油萃取脱硫工艺研究 摘 要 利用过氧化氢为氧化剂甲酸为催化剂无机硫酸为助催化剂结合超声波强 化技术脱除柴油中的硫化物研究了不同的氧化条件对柴油脱硫率的影响重点 考察了不同萃取剂萃取时间萃取温度剂油比和萃取级数等萃取条件对柴油 脱硫效果的影响确定了柴油最佳氧化与萃取脱硫反应的工艺条件 实验结果表明 以 90 DMF 作萃取剂时萃取效果最为理想随着萃取时间 的增加脱硫率逐渐升高30min 时脱硫率满足生产要求由于柴油以及萃取剂特点 和工业生产等因素萃取温度选为室温下柴油硫含量会随萃取级数增加而降低 剂油比减小脱硫率而下降 当过氧化氢甲酸硫酸试剂用量比 123 1515氧化温度 70℃氧化 时间 60min100超声波强化萃取剂用 90的DMF 剂油比为 11室温萃 取时间 30 min二级萃取条件下硫含量可降到 10 以下的零硫柴油标准 ngμl 关键词 柴油萃取氧化脱硫 -I- 柴油萃取脱硫工艺研究 Study on the desulfurization of diesel fuel by oxidative extraction Abstract Using hydrogen peroxide as the oxidant formic acid as the catalyst inorganic sulfate to help catalyst with enhanced ultrasound technology diesel removal of sulfides Study the different conditions of the desulfurization rate of diesel mainly inspected the different extraction agent extraction extraction temperature and extraction of oil than the series and other extraction conditions the effects of diesel desulfurization to determine the best diesel oxidation And the extraction of the desulfurization process The results showed that 90 DMF to make extraction of extraction at the effect of the most ideal time as the extraction of the desulfurization rate of increase gradually increased 30 min the desulfurization rate to meet production requirements due to diesel and extraction of features and factors such as industrial production extraction As the temperature at room temperature sulfur content of diesel will increase the extraction levels lower than the decrease of oil desulfurizatio