塑性变形条件下16MnR钢的CO2腐蚀电化学行为.PDF

16M nR CO 2 59 16MnR CO 2 Electrochem ical Cor rosion Behavior of 16M nR St eel w ith Plast ic Strain in CO2 E nvir onment , , ( , 100083 SU N Jianbo , L IU Wei, L U M inxu ( Scho ol of Mat erials Science and Eng ineer ing, U niv ersit y o f Science and T echnolo gy Beijing , Beijing 100083, China : , CO 2 , 16M nR CO 2 : , , , 16M nR CO2 , , 16M nR , , : CO2 ; ; ; ; : T G 1729 : A : 100 14381( 2009 Abstract: Oil country t ubular goo ds oft en service under st ress and st rain condit ions. In order t o inv es t igat e t he ef f ect of st ress and st rain o n CO2 cor rosion behavior of 16M nR st eel, electro chemical m eas urement t echniques w er e employ ed t o det ermine t he electr ochemical im pedance spect ra( EIS , linear po lariz at ion resist ance( LP R and corro sion pot ential( E corr af t er diff erent plast ic def ormat ion. T he re sults sho w t hat t he cor rosio n pot ent ial shif ts in neg at ive direction , linear polarization r esist ance de creases, and co rrosion r at e increases w ith increasing str ain . T he Nyquist plot s of EIS spect ra under tensile and com pressive st rain exhibit t w o semicircles : a f irst capacit ance loo p at high f requency and a second induct ance loo p at low fr equency. T he dist ance alo ng the real ax is w her e t he t w o lo ops appears decrease