硫化物纳米和微晶材料的溶剂热合成及其机理研究-无机化学专业论文.docxVIP

AbstractsIn Abstracts In this dissertation，hydrothermal and solvothem_lal technique for the synthesis of inorganic materials were developed，we report a solvothermal route to synthesize Bi2S3 nanowires adopting an inorganic-surfactant(BiCId-CTA+)lamellar structure as precursors and water,ethanol as solvents respectively．CdS nanocrystals were synthesized in hydrothermal systems and then were recrystallized to obtain CdS hexagon tubular microerystals．The ZnS hollow microspheres composed by many small ZnS nanopartictes were synthesized successfully in hydrothermal．ethanol systems and the gas S02 produced in our reaction process acted as a soft template． The good disperse MnFe204 nanocrystals were synthesized successfully in hydrothermal-glycol systems adopting MnO(OH)nanowires as precursors by a modifying CO—precipitation method．The main points can be summarized as follows： t，The surfactants are introduced into the solvothermal technique．It WaS reported that the BiCl4。could react with eTA+to form BiCl4_-C1’A+lamellar structure．we adopted the Iamellar BiCl4-JCTA+as a precursor您r formation the lamellar Bi2S3 firstly．Moreover,much evidence demonstrates that lamellar structures，regardless of whether they are natural or artificial，have a strong tendency to form wires or tubes．With the increase ofthe reaction time，the lamellar Bi2S3 begin to roll onto them and formed nanowires bundles．And finally the naowires bundles were separated幻form uniform single nanowires．This reliable method call be controlled and is expected to be applicable to the preparation ofq D nanostruetures ofother inorganic compounds，such as the Sb2S3 nanowires in our experiment 2．Hydrothermal preparative technique was developed．CdS nanocrystals were firstly synthesized，and then recrystallizing the nanocry鞋als by controlling the temperarure，mineralizer concentration and the fill factor grew the hexagon 2 tubular tubular microcrystal CdS．Moreover，the ZnSe microcrsta]s were also synthesized successfully by