浸没式厌氧平板MBR处理酒厂废水的研究.docVIP

第22卷 第22卷增刊 中国给水排水 V01．22 Suppl· 2006年9月 CHINA WATER＆WASTEWATER Sep．2006 浸没式厌氧平板MBR处理酒厂废水的研究 王志伟， 吴志超， 顾国维， 俞国平 (同济大学污染控制与资源化研究国家重点实验室，上海200092) 摘要： 采用小试规模的浸没式厌氧平板MBR对高浓度酒厂废水进行处理，研究了MBR的 处理效果及膜污染的特性。考察了COD负荷、HRT、VFA和碱度等与污染物的去除特性，同时考察 了阻力分布，并采用离心分离方法研究了污泥的三组分对膜污染的影响。试验结果表明，COD负 荷为5．2～8．0 ks／(m’·d)、水力停留时间为3—5 d时，MBR对COD的平均去除率为95％。正常 运行时的碱度与VFA的比值为2．5～4．5。当COD负荷超过10．0 ks／(m3·d)，系统VFA出现累 积，COD处理效果下降。水力停留时间对厌氧MBR处理效果有重要影响，水力停留时间应大于70 h。膜污染模型的推导也证实了厌氧MBR膜污染属于泥饼阻力模型；膜阻力分布的测定表明，浓差 极化阻力和泥饼层阻力是膜污染的主要部分；污泥组分中污泥悬浮固体颗粒是膜污染的主要因素。 关键词：废水处理； 浸没式厌氧膜一生物反应器； 酒厂废水；膜污染 中图分类号：X703．1 文献标识码：A 文章编号：1000—4602(2006)增刊一0012—06 Study on a Submerged Anaerobic MBR for Treatment of Alcohol- distillery Wastewater WANG Zhi—wei， WU Zhi—chao， GU Guo—wei， YU Guo-ping (State Key Laboratory of Pollution Control and Resource m嬲e，Tongfi University，Shanghai 200092，China) Abstract： A flat—-sheet style anaerobic membrane bioreactor was applied high·-strength alco·- hol-distillery wastewater in order investigate pollutant removal efficiency and membrane fouling proper- ties．The relationship between volumetric organic load(VOL)，HRT，VFA，alkalinity and the pollutant removal was studied；in the meantime，membrane resistance distribution and the contribution of three sludge fractions membrane fouling were also studied．Test results suggested that COD removal efficien— cy average was 95．0％，with VOL 5．2—8．0 ks／(m3·d)and HRT 3—5 d．During steady—state peri— od，ratio of alkalinity with VFA was about 2．5—4．5．When VOL was 10．0 ks／(m3·d)，VFA of the system increased acutely and COD removal efficiency decreased．HRT had important effect COD removal efficiency and proper HRT for the anaerobic MBR was 70 h．Membrane resistance model of the anaerobic MBR belonged cake resistance model． Membrane resistance distribution analy— sis suggested that the concentration polarization and sludge cake resistance were the main parts of mem— brane resistance．The suspended microbial solids of three sludge fractions were