加碱处理PAC污泥的释磷机理及磷回收研究.PDF

中国环境科学 2017,37(9) ：3407~3415 China Environmental Science 加碱处理 PAC 污泥的释磷机理及磷回收研究 * 许德超 ,周礼杰,尹魁浩,彭盛华,成 功,周廷尧 (深圳市环境科学研究院国家环境保护饮用水水源地管理技 术重点实验室,深圳市饮用水水源地安全保障重点实验室,深圳市水环境中新型污染物检测与控制重点实验室,广东 深圳 518001) 摘要： 以加碱处理 PAC 污泥,考察了不同 pH 条件下污泥破解情况,研究了污泥中磷和铝的释放以及磷形态分布与变化以分析污泥释磷机 理,最后对释放的磷进行回收.结果表明,相比于 pH=11 、12,pH=13 更有效地促使污泥细胞破解和 DNA 释放,240min 后细胞破解率达 96.9%. 同时,SOP(溶解性正磷酸盐, 以 PO3- -P 计)大量释放,其中大部分来源于磷酸铝和氢氧化铝的溶解.调节污泥初始 pH=13,240min 后污泥中 4 91.2% 的 NAIP( 非磷灰石无机磷)和 69.2% 的 OP(有机磷)溶解释放.对加碱处理后的污泥脱水,取脱水滤液进行磷回收,pH=9.5,Ca/P=3 时,30min 后磷回收效果可达 82.4%.研究认为,通过加碱促使 PAC 污泥大量释磷并回收,效果好、运行简单,具有实际应用潜力. 关键词：加碱处理；PAC 污泥；释磷；磷回收 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2017)09-3407-09 Alkaline treatment of PAC (polyaluminum chloride) excess sludge: Study on mechanism of phosphorus release and * phosphorus recovery. XU De-chao , ZHOU Li-jie, YIN Kui-hao, PENG Sheng-hua, CHENG Gong, ZHOU Ting-yao (State Environmental Protection Key Laboratory of Drinking Water Source Management and Technology, Shenzhen Key Laboratory of Drinking Water Source Safety Control, Shenzhen Key Laboratory of Emerging Contaminants Detection Control in Water Environment, Shenzhen Academy of Environmental Sciences, Shenzhen 518001, China). China Environmental Science, 2017,37(9)：3407~3415 Abstract ：The sludge disintegration under different pH conditions in alkaline treatment of PAC excess sludge was investigated. In addition, the phosphorus release mechanism was identified with both releasing process of phosphorus and aluminum, including the distribution and variation of phosphorus forms. Finally, phosphorus recovery was carried out. The results demonstrated that more DNA release and higher cell cracking rate (96.9% after 240min alkaline treatme