刘中民酸碱催化课课件（下）.ppt

SAPO-34分子筛合成实例 解决的基础问题 Si 原子是如何进入分子筛骨架的 如何控制 Si 原子在分子筛骨架中的分布 XRD spectra of as-synthesized samples Crystallization curve of SAPO-34 IR results Assignment of the IR bands in framework vibration region of the as-synthesized samples 31P NMR of the gel samples in the first steps of the crystallization process The stirred mixing gel of the raw sources (silica sol, pseudoboehmite, orthophosphoric acid and water) The stirred mixing gel of a. and template (TEA). The b. gel after aging (the initial state of the crystallization). 27AlMAS(a), 31P MAS(b) and 29Si CP/MAS(c) NMR spectra of as-synthesized