十八烷氧基-羟基丙基.PDF

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2019, 9(2), 73-80 Published Online March 2019 in Hans. /journal/hjcet /10.12677/hjcet.2019.92012 Synthesis of N-(3-Octadecanoxy-2-Hydroxy-Propyl)-N,N- Dihydroxyethyl Amine Oxide Bing Zheng, Minghui Ouyang, Yang Dong, Haomiao Yu, Jiaqi Yi, Rongming Zhang College of Chemistry Chemical Engineering, Northeast Petroleum University, Daqing Heilongjiang th th th Received: Jan. 29 , 2019; accepted: Feb. 8 , 2019; published: Feb. 15 , 2019 Abstract In this paper, using octadecanol, epichlorohydrin, diethanolamine and hydrogen peroxide as raw materials, N-(3-octadecyloxy-2-hydroxypropyl)-N-N-dihydroxyethyl amine was synthesized by three-step reaction. The effects of reaction time, catalyst and other factors on the yield of the product were determined, and the optimum reaction conditions were determined. The opti- mum conditions for the formation of 3-octadecyloxy-2-hydroxy-1-chloropropane were as fol- lows: sodium hydroxide was used as catalyst; the molar ratio of reactants is 1:1.1; the temper- ature of dropping epichlorohydrin is 65˚C; the time of dropping is 1.5 h; the reaction tempera- ture is 95˚C and the reaction time is 5 h. The optimum conditions for the formation of N- (3-octadecyloxy-2-hydroxypropyl)-N-N-dihydroxyethyl tertiary amine were as follows: reaction temperature 85˚C; molar ratio of reactants 1:1.2; reaction time 4 h. The optimum reaction condi- tions of N-(3-octadecyloxy-2-hydroxypropyl)-N-(N-dihydroxyethyl) amine and hydrogen peroxide were as follows: 1:1.1 mol ratio of reactants was 1:1.1 when hydrogen peroxide was dripped at