锆钛比对铁铌锆钛酸铅热释电陶瓷结构与性能的影响研究.doc

PAGE 1 不同锆钛比铁铌锆钛酸铅热释电陶瓷结构与性能 江 凤1，蔡 锴2，邓平晔2, 王云丽1，郭 栋1 中国科学院声学研究所，北京，100190；2. 北京市理化分析测试中心，北京, 100089) 摘要：研究了Zr/Ti摩尔比对两步法合成的0.3Pb(Fe1/2Nb1/2)O3–0.7Pb(ZrxTi1?x)O3 (PFNZxT1-x)复合热释电陶瓷微观结构、相构成和综合电学性能的影响。结果表明，所制备的陶瓷样品均为单一钙钛矿结构。在x=0.50处出现四方、菱方相共存的准同型相界。随着Zr/Ti摩尔比增加(x从0.50增至0.95)，逐渐从两相共存变为菱方相，同时伴随晶胞体积和陶瓷晶粒尺寸的不断增大。随x增加，体系介电常数减小，介电损耗变化不大，而体系热释电系数及优值呈现出逐渐增大趋势。当Zr/Ti摩尔比在富锆的80/20~85/15之间时，材料室温热释电系数p大于11×10?8 C·cm?2·K?1，探测率优值FD大于16×10?5 Pa?1/2，具有较好的综合电学性能。 关键词：锆钛摩尔比；热释电陶瓷；热释电性能；铁电性能 中图分类号：TQ 304.9 文献标志码：A 文章编号：0454–5648(2015)09– – Microstructure and Electrical Performance of 0.3Pb(Fe1/2Nb1/2)O3–0.7Pb(ZrxTi1?x)O3 Pyroelectric Ceramics with Different Zr/Ti Ratios JIANG Feng1，CAI Kai2，DENG Pingye2，WANG Yunli1，GUO Dong1 (1.Institute of Acoustics, Chinese Academy of Sciences, Beijing 100190, China; 2. Beijing Center for Chemical and Physical Analysis, Beijing 100089, China) Abstract: The microstructure and electrical performance of 0.3Pb(Fe1/2Nb1/2)O3–0.7Pb(ZrxTi1?x)O3 pyroelectric ceramics with various Zr/Ti molar ratios prepared by a wolframite method were investigated. The results by X-ray diffraction indicate that the as-prepared ceramics have a single perovskite phase structure. The sample with x of 0.50 shows a morphotropic phase boundary with coexisted tetragonal and rhombohedral phase.The lattice structure changes from the coexistence of tetragonal and rhombohedral phase to single rhombohedral phase when Zr/Ti molar ratio (x increases from 0.50 to 0.95) increases. Meanwhile, the samples exhibit the increased lattice volume and the greater grain size. The dielectric constant of sample decreases, the pyroelectric coefficient and the figure of merit increase and the dielectric loss is rather stable when the Zr/Ti molar ratio increases. The enhancement of the pyroelectric performance with increasing Zr/Ti molar ratio is attributed to the improved spontaneous polarization at various temperatures. The samples have the optimum pyroelectric performance at a Zr/Ti molar r