乙烯三聚催化剂预混探究.docxVIP

乙烯三聚催化剂预混探究 摘要：乙烯三聚四元催化剂由中心金属A、含氮配位体B、 烷基铝D和促进剂卤化物C组成，根据四种组分不同的配制 方式，旨在实现提高催化剂的活性、选择性以及产品的正构 率，降低成本，采用催化剂部分预混方式，1-己烯正构率达 到99. 35%。催化剂预混适合比例时产品的正构率能够完全满 足生产要求。 Abstract : Ethylene trimerization catalyst is composited by central metal A, nitrogen-containing ligand B, alkyl aluminum D and accelerators halide C, according to the differe nt prepara tion pat tern of four components, it is intended to improve the catalyst? s activity, selectivity and product n-rate, reduce costs. 1-hexene n-rate reached 99.35% with the use of the catalyst partially premixed mode? In the condition of the suitable pro