丝光沸石分子筛上二甲醚羰基化合成乙酸甲酯分析.pdfVIP

ABSTRACT Ethanol is regarded as one of the promising alternative fuels and has a broad application prospects. In recent years, the production of ethanol attracts the widespread attention. Based on a novel ethanol synthesis routes (dimethyl ether (DME) carbonylation – methyl acetate (MA) hydrogenation), we mainly investigated the carbonylation of DME over Mordenite (MOR) in this work. Upon increasing the temperature to 220 C, the conversion of DME over commercial H-MOR (H-MOR-C) increased, and the maximal DME conversion of 74.0% was obtained at 220 C. However, serious coking at higher temperature resulted in the deactivation of the catalyst. The optimal reaction temperature, was obtained at 180 C that the H-MOR possessed better stability and DME conversion remained at 20.0%. Thereafter, we investigated the carbonylation of DME over the H-MOR supported copper prepared by ion exchange method (IE-Cu) and solid state reaction method (SSR-Cu). The results showed that the sample IE-Cu exhibited the higher catalytic activity because most of copper cations existed in the zeolite channels, and the DME conversion reached 36.9%. While the sample SSR-Cu exhibited lower activity (only 6.7%) because most of copper was in the form of CuO on the zeolite surface. In order to further improve the catalytic performance of H-MOR, we synthesized the H-MOR catalyst by the hydrothermal method. The as-prepared H-MOR (H-MOR-S) was more uniform in morphology