聚己内酯的甲醇解聚工艺.pdf

第 16 卷第 6 期 过 程 工 程 学 报 Vol.16 No.6 2016 年 12 月 The Chinese Journal of Process Engineering Dec. 2016 聚己内酯的甲醇解聚工艺 * 江 艳， 谢传欣 ， 刘 艳， 郭 丹 (青岛科技大学环境与安全工程学院，山东 青岛 266000) 摘 要：研究了聚己内酯的甲醇解聚反应条件，采用气相色谱质谱联用仪对解聚产物定性分析，采用气相色谱仪对解聚产物定 量分析. 结果表明，聚己内酯在常压下解聚，在甲醇:聚己内酯: 自制催化剂质量比80:10:0.18、反应温度 313 K、反应时间2 h 的 条件下，聚己内酯解聚率达 97.11%，解聚产物主要为- 己内酯和6-羟基己酸甲酯的混合物. 关键词：聚己内酯；甲醇；解聚；6-羟基己酸甲酯；- 己内酯 中图分类号：TQ342.21, TQ323.41 文献标识码：A 文章编号：1009606X(2016)06099705 DOI: 10.12034/j.issn.1009-606X.216188 Methanol Depolymerization Process of Polycaprolactone * JIANG Yan, XIE Chuan-xin , LIU Yan, GUO Dan (Environmental and Safety Engineering Institute, Qingdao University of Science and Technology, Qingdao, Shandong 266000, China) Abstract: The reaction conditions to depolymerizate polycaprolactone by methanol were investigated. The depolymerizated products were analyzed for qualitative analysis by gas chromatographymass spectrometry, and they were analyzed for quantitative analysis by gas chromatograph. Polycaprolactone was depolymerizated at atmospheric pressure and results showed that depolymerization rate of polycaprolactone could be 97.11% when the depolymerization conditons as followed: The mass ratio of methanol: polycaprolactone: home- made catalyst was 80:10:0.18, reaction temperature was 313 K and time was 2 h, the depolymerization products were the mixture of - caprolactone and 6 hydroxy acid methyl caproate. Key words: polycaprolactone; methanol; depolymerization; 6 hydroxy acid methyl caproate; -caprolactone