Al2O3对艾萨余热锅炉辐射区结渣熔融特性影响.docVIP

doi：10.3969/j.issn.1007-7545.2019.02.003 doi：10.3969/j.issn.1007-7545.2019.02.003 黄晓艳1,2，胡建杭1,2 (1.省部共建复杂有色金属资源清洁利用国家重点实验室，昆明 650093) (2.昆明理工大学 冶金与能源工程学院，昆明 650093) 摘要：以某铜冶金艾萨熔炼炉余热锅炉辐射区结渣为研究对象，研究了Al2O3在高温下对渣样熔融特性的影响。结果表明，渣样熔融温度随着Al2O3比例(1%~16.7%)的提高而提高，当Al2O3达到16.7%、温度1 370 ℃时，渣样并没有出现软化状态。添加16.7%的Al2O3的渣样在1 100 ℃灼烧1 h，渣样中大部分仍为Fe3O4，只有微弱的铁铝尖晶石峰出现；当灼烧温度达到1 200 ℃时，铁铝尖晶石的特征峰较为明显，即生成了大量铁铝尖晶石。通过FactSage 7.2进行的热力学反应平衡计算结果与XRD结果一致。 关键词：Al2O3；余热锅炉；辐射区；结渣；熔融特性；艾萨法 中图分类号：TF811; TK224.9 文献标志码：A 文章编号：1007-7545（2019）02-0000-00 Effect of Al2O3 on Fusibility of Slag in Radiation Zone of ISA Waste Heat Boiler HUANG Xiao-yan1,2, HU Jian-hang1,2 (1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization，Kunming 650093, China; (2. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) Abstract：With slag in radiation zone of copper smelting waste heat boiler as research object, effect of Al2O3 addition on fusibility of slag samples at high temperature was studied. The results show that melting temperature of slag sample rises with increase of Al2O3 ratio (1%~16.7%). When Al2O3 reaches 20 % at temperature of 1 370 ℃, the slag sample does not present softening state. Slag samples with 16.7% Al2O3 addition were kept being burned for one hour at 1 100 ℃, most of the slag samples are still in Fe3O4 phase, and only weak Fe-Al spinel peaks appear. The characteristic peaks of Fe-Al spinel are more obvious when temperature reaches 1 200 ℃, that is, a large amount of Fe-Al spinel is formed at the target temperature. Thermodynamic equilibrium calculation results carried out by Fact Sage 7.2 accord with XRD results. Key words：Al2O3; waste heat boiler; radiation zone; slag; fusibility; ISA Process 当前铜冶炼仍以火法为主，其产量约占世界铜总产量的80%。艾萨熔炼法通过从炉顶插入熔体的喷枪喷入富氧空气，浸没喷射产生湍动熔池，使氧化反应或还原反应激烈地进行。艾萨熔炼强度大、炉料准备简单，同时产生的烟气温度较高(1 200 ℃)[1]。为降温除尘、回收烟气余热和环保，需配备余热锅炉[2]。艾萨炼铜余热锅炉属于多烟道式，分为辐射冷却区、连接段及对流受热区[3]。锅炉烟道的结渣是余热锅炉普遍存在的问题，尤其是辐射冷却区的结渣尤为突出。从某