原子分子光谱学.ppt

wbt * Chapter 10. REMPI, ZEKE, and MATI Spectroscopies Resonance-enhanced multiphoton ionization (REMPI) spectroscopy involves more than one photons in the ionization process. In general, the REMPI process occurs by a resonant m-photon excitation from a ground electronic state to an excited (ro)vibronic state. from a ground electronic state to an excited state and n photons from the neutral excited state to and ionic state. More (n) additional photons are then absorbed and the molecule is ionized. The probability of ionization is enhanced by the fact that the first m photons are resonant with