固相聚合合成聚噻吩衍生物及烷基链对固相聚合的-IngentaConnect.PDF

物理化学学报(Wuli Huaxue Xuebao) 2550 Acta Phys. -Chim. Sin. 2017, 33 (12), 2550−2558 December   [Article] doi: 10.3866/PKU.WHXB201706071 固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响 裴 童 彭 凯 蔡心怡 袁良杰* 夏江滨* (武汉大学化学与分子科学学院，武汉 430072) 摘要：本文以EDOT-CH(R)-EDOT为基本模型，向侧链引入噻吩、咔唑、芴等几种典型的光电基团，并通 过固相/熔融聚合得到相应的聚合物。详细探讨了聚合物的相关性质和几种典型单体的晶体结构，同时发现 烷基链的引入降低了分子间的作用力，使得单体的初始聚合温度(T )降低。 onset 关键词：聚噻吩衍生物；固相/熔融聚合；烷基链影响 中图分类号：O646 Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization PEI Tong PENG Kai CAI Xin-Yi YUAN Liang-Jie* XIA Jiang-Bin* (College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, P. R. China) Abstract: New poly(bis-3,4-ethylenedioxythiophene methine)s derivatives with typical electro-optical moieties of thiophene, carbazole and fluorene as the side chains are obtained by facile solid state polymerization (SSP) or melt state polymerization (MSP). Detail characterizations of these polymers are carried out and some key monomersʹ crystals are obtained for structures analysis. It is found that existence of alkyl chains decrease monomers onset temperatures for SSP (T