GASES Free Response worksheet英文文献资料.pdf

AP* Gas Law Free Response Questions 1971 2 HCOONa + H SO → 2 CO + 2 H O + Na SO 2 4 2 2 4 A 0.964 gram sample of a mixture of sodium formate and sodium chloride is analyzed by adding sulfuric acid. The equation for the reaction for sodium formate with sulfuric acid is shown above. The carbon monoxide formed measures 242 milliliters when collected over water at 752 torr and 22.0°C. Calculate the percentage of sodium formate in the original mixture. 1971 At 20°C the vapor pressure of benzene is 75 torr, and the vapor pressure of toluene is 22 torr. Solutions in both parts of this question are to be considered ideal. (a) A solution is prepared from 1.0 mole of biphenyl, a nonvolatile solute, and 49.0 moles of benzene. Calculate the vapor pressure of the solution at 20°C. (b) A second solution is prepared from 3.0 moles of toluene and 1.0 mole of benzene. Determine the vapor pressure of this solution and the mole fraction of benzene in the vapor. 1972 A 5.00 gram sample of a dry mixture of potassium hydroxide, potassium carbonate, and potassium chloride is reacted with 0.100 liter of 2.0 molar HCl solution. (a) A 249 milliliter sample of dry CO gas, measured at 22°C and 740 torr, is obtained from the reaction. What is 2 the percentage of potassium carbonate in the mixture? (b) The excess HCl is found by titration to be chemically equivalent to 86.6 milliliters of 1.50 molar NaOH. Calculate the percentages of potassium hydroxide and of potassium chloride in the original mixture. 1973 A 6.19 gram sample of PCl is placed in an evacuated 2.00 liter flask and is completely vaporized at 252°C. 5 (a) Calculate the pressure in the flask if no chemical reaction were to occu