线型缩聚物的分子量与分子量分布.pptVIP

Closed system： = + 1 Self-Catalyzed system： = 2k3 t + 1 With the same mole ratio of groups ： Key: Deactivation of the functional end groups, i.e., stabilization of molecular weight For the systems of a-R-a + b-R‘-b, not a-R-b The total of macromolecules The extent of reaction of group a is given by Pa Reacted a ： NaPa b : NaPa Unreacted a ：Na(1－ Pa) b : Nb － NaPa Theoretically, if the mole ratio of the two functional groups in the systems of a-R-a + b-R‘-b can be kept equal，the average degree of the condensation polymer will reach the maximum to the end of reaction. The Excessive percentage q of b-R‘-b molecule is often used besides r. The q is defined as: R-b can react with group a in the polymer. By this method, the end groups are captured, giving the stabilized molecular weight. The molecular weight of polymer can be adjusted by R”-b. This method can be used for both the system a-R-a / b-R’-b and the system of a-R-b. ① The systems of a-R-a + b-R‘-b with  the same mole ratio ② The system of a-R-b The high purity of monomer Precise measurement Proper temperature control Protected by inert gas, along with using catalytic agent and vacuumizing the system The molecular weight distribution (also called Polydispersity Index) is then given by: * Polymer chemistry  Factors Influence on the Molecular Weight Molecular Weight Control in Linear Polycondensation Molecular Weight Distributions in Linear Polycondensation Part 3 Molecular Weight and MWD Unclossed system： = The Factors Influence on the Molecular Weight of Polycondensation The Balanced Characteristic External Catalysis system： = k2C0t + 1 The Catalyzed System = The Extent of Reaction Molecular Weight Control in Linear Polycondensation One way is slightly over weight of one reactants (non-stoichiometric). Finally