二氧化钛复合膜电极检测三聚氰胺tcy.docVIP

PAGE PAGE 1 PAGE 1 Nafion/二氧化钛复合膜电极检测多巴胺 Nafion/tio2 composite film electrodes detection of dopamine 摘 要 化学修饰电极是上世纪下半页发展起来的一门新兴学科，现阶段在电化学和电分析化学方面应用较多。目前应用十分广泛，主要有食品分析、环境科学，以及生物领域。另外分析化学及材料学方面也有很重要的应用。聚合物修饰电极可以有目的的在电极表面固定特定的的官能团，从而使电极具有特定的性质。化学修饰电极制备的方法比较简单，电极寿命相对较长，从而有广泛的应用。 化学修饰电极是由导体或半导体制作的具有特殊性能的电极，通过在电极表面固着单分子、多分子、离子或者是聚合物的化合物薄膜，接消耗电荷反应而呈现出该修饰电极的特殊性质。也就是说在电极表面经过分子设计，被人为的加工成修饰电极。其中包括对电极界面区的化学改变，所以对电极进行修饰所用的物质不同，化学修饰电极具有的特性不同。 对于化学修饰电极电极的研究和制作，对于电极过程动力学理论的发展有重要意义，可以说开拓了一个化学研究的新领域，具有非常广阔的应用前景和经济环境效益。 通过滴涂法制备了Nafion/TiO2复合膜修饰电极，并利用该电极选择性检测了多巴胺，线性范围为1.0×10-11 – 6.0×10-7 M范围能线性相关，相关系数为0.997检出限为10 pM。 关键词：二氧化钛复合膜电极；多巴胺；电化学检测；化学修饰电极 ABSTRACT Chemically modified electrode is developed in the mid - 1970 - s latest a discipline, is the current active frontier of electrochemistry and electrochemical analysis. They are widely used at present, mainly in food analysis, environmental science, and biology. Analytical chemistry and material science also has very important application. Polymer modified electrodes can be targeted on the electrode surface functional groups of fixed choice, make the electrodes have specific properties. Chemical modified electrode preparation method is simple, the electrode life is long, thus has a wide range of applications. Chemically modified electrode is made of a conductor or semiconductor electrode with special performance, on the electrode surface by fixation of single molecules, many molecules, ions, or is a compound of polymer film, connect consumption charge reaction and presents the special properties of the modified electrodes. On the electrode surface that is through molecular design, artificially processed into modified electrodes. Including the chemical change of the electrode interface area, so by modifying the electrodes used in the material is different, the characteristics of chemical modified electrodes with different. For research and production of chemically modified electrode electrode, greatly promote