巯基苯并噻唑对铜缓蚀行为的表面增强红外光谱研究-物理化学学报.pdf

物理化学学报(Wuli Huaxue Xuebao) December Acta Phys. -Chim. Sin. 2013, 29 (12), 2565-2572 2565 [Article] doi: 10.3866/PKU.WHXB201310294 2-巯基苯并噻唑对铜缓蚀行为的表面增强红外光谱研究 霍胜娟* 陈利红 祝 卿 方建慧 (上海大学理学院化学系, 上海200444) 摘要: 2-巯基苯并噻唑(MBT)是Cu 的高效缓蚀剂, 但是缓蚀机理存在较大争议. 本文通过电化学极化曲线从 宏观角度对缓蚀效率进行评估, 并利用原位衰减全反射-表面增强红外光谱技术结合理论计算研究了电位控制 下的微观吸附构型. 结果表明: 在较高电位(大于0 V, 相对饱和甘汞电极(SCE))下, MBT 和金属Cu 之间发生电 子转移, MBT 以硫醇式的环外S 和N 与金属Cu(I)离子配位在表面形成聚合物膜; 在较低电位(小于0 V, vs SCE)下, MBT 通过环外S 原子以硫醇离子形式在金属Cu 表面直立吸附. 表面膜阻止了腐蚀介质的侵蚀, 起到 了较好的缓蚀效果. 关键词: 表面增强红外光谱; 衰减全反射; 2-巯基苯并噻唑; 铜; 缓蚀机理 中图分类号: O646; O647 Surface-Enhanced Infrared Absorption Spectroscopy Study of Anticorrosion Behavior of 2-Mercaptobenzothiazole on Copper HUO Sheng-Juan* CHEN Li-Hong ZHU Qing FANG Jian-Hui (Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, P. R. China) Abstract: 2- Mercaptobenzothiazole (MBT) is a highly efficient inhibitor of Cu. However, the inhibition mechanism is still unclear. In this paper, the anticorrosive effect of MBT on a Cu surface at the macroscopic level was evaluated using a polarization curve technique. The potential-dependent adsorption geometries of MBT at the molecular level were investigated using electrochemical surface-enhanced infrared reflection absorption spectroscopy in attenuated total reflection mode, together with theoretical calculations. The results indicated that the MBT molecules were adsorbed on the Cu surface vertically, in a thiolate form, through exocyclic S atoms at a potential negative of 0 V (vs s