常压液相法一步合成铌掺杂二氧化钛-IngentaConnect.pdf

40 10 – 1515 40 10 Vol. 40No. 10 2 0 1 2 1 0 JOURNAL OF THE CHINESE CERAMIC SOCIETY October2012 ( 200237) (1--3-)X – TiO Nb5+Nb 5% () 2 O614 A 0454–5648(2012)10–1515–04 2012–09–27 9:48:31 /kcms/detail/11.2310.TQ0948.201210.1515_024.html One-Step Synthesis of Niobium-Doped TiO in Atmospheric Pressure under 2 Liquid Phase Conditions FANG Bin DONG Bo YANG CunzhongYANG XiangmingGE Xueping (Institute of Nuclear Technology and Application, East China University of Science and Technology, Shanghai 200237, China) Abstract: Niobium-doped titanium dioxide (TiO2) was synthesized under atmospheric pressure from titanium tetrachloride and nio- bium pentachloride with ionic liquid (1-ethyl-3-methyl-imidazole-acetate) as a solvent. The doped TiO2 was characterized by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy, respectively. The influence of Nb on the optical absorp- tion and apparent dielectric constant was investigated. The results reveal that the products possess an anatase crystallinity and the optical absorption edge of the UV spectrum appears blue shift when Nb5+ is doped into TiO . In addition, the apparent dielectric con- 2 stant of TiO2 increased after Nb was doped, and became the maximum at the amount of Nb of 5% (mole fraction). Key words: ionic-liquid; atmospheric pressure; Nb-doped titanium dioxide; dielectric constant TiO [1] 2 TiO2 [2,3]