应用量子点改善染料敏化太阳能电池效率之研究.doc

應用量子點改善染料敏化太陽能電池效率之研究 Applications of the Quantum Dot in Improving the Efficiency of Dye-Sensitized Solar Cells 研究生：周峰丞 Chou, Feng-Cheng 指導教授：周春禧 Chou, Chuen-Shii 【摘要】 本研究採用水解法，製備具有量子點硫化鉛(Quantum Dot PbS)之二氧化鈦複合粉體，藉以改善染料敏化太陽能電池之光電轉換效率。首先，製備具有0.05M、0.005M之硫化鉛複合粉體，並將FTO導電玻璃浸泡於0.05M的四氯化鈦溶液後，並旋塗面積0.25cm2的二氧化鈦薄膜，並以450℃高溫燒結，接著將此工作電極旋塗複合粉體薄膜(或浸泡0.05M的四氯化鈦溶液)，再以450℃高溫燒結。將完成之工作電極浸泡於N719染料6小時，恆溫70℃。接著將工作電極與相對電極(Pt)封裝成染料敏化太陽能電池。最後，將所製備的染料敏化太陽能電池，使用XES-310S 300W的太陽光源模擬器與I-V量測系統，量測染料敏化太陽能電池的Voc、Jsc、F.F.與η。本研究證實，使用水解方式製備之TiO2/PbS複合粉體薄膜，可以避免硫化鉛與電解液直接接觸，產生反應、腐蝕，而能提昇整體染料敏化太陽能電池對光的吸收波段，及光電轉換效率。本實驗之對照組W6-TiO2(P-25)的光電轉換效率為5.11%，而具有複合粉體薄膜修飾之染料敏化太陽能電池，效率可達6.05%。 關鍵字：硫化鉛、染料敏化太陽能電池、二氧化鈦、水解法、FTO導電玻璃 【Abstract】 This study investigates the application of the Quantum Dot in improving the efficiency of dye-sensitized solar cells (DSSC). An electrode prepares the different Molar concentration composite particles of TiO2 (P-25) and PbS through hydrolysis. Coating the colloid on the FTO (immersed 0.05M TiCl4 aqueous solution) substrate forms a thin film of titanium dioxide then sintered by High Temperature Furnace. The next step is to coat the colloid on the control group (immersed 0.05M TiCl4 aqueous solution) substrate to form the TiO2/PbS thin film and then sintered by High Temperature Furnace. The area is 0.25 cm2.The working electrode with a TiO2/PbS thin film was coated with the N-719 (Ruthenium) by immersing the plates in a warm (70℃) solution of this dye for 6 hours. In addition, a thin film of platinum was deposited on the FTO-glass substrate of the counter electrode. Finally, the Dye-Sensitized Solar Cell (DSSC) was assembled, and the short-circuit photo-current, the open-circuit photo-voltage and the power conversion efficiency of DSSC were measured using a XES-310S 300W I-V measurement system. This study proved that using the method of hydrolysis to make TiO2/PbS and composite particles is able to avoid Quantum Dot, PbS, and direct contact of electrolyte solution direct cont