影响配合物稳定性因素的概述.pdfVIP

包头师范学院 本科学年论文 题 目：影响配合物稳定性因素的概述 学 生 姓 名：李本元 学 院：化学学院 专 业：应用化学 班 级： 08 级应用化学（ 2）班 指 导 教 师：周毅 教授 二○一○ 年 七 月 摘 要 本文从中心体、配体、外界条件三个方面来讲述了影响配合物稳定性的因素。 中心体对配合物稳定性的影响主要是体现在中心离子与配体之间结合能力的强 弱，而中心离子影响这一能力的因素有中心离子的价电子层结构、 电荷、离子半 径、极化作用等； 而配体和外界条件也是通过影响配合物的微观结构来影响配合 物的稳定性。 关键词： 中心体；金属离子；配体；螯合效应 Abstract From the center body, ligand, three aspects about the external conditions that affect the stability of the complex factors. Centrosome of the complexes affected mainly reflected in the central ion and ligand binding ability between the strength, the center ion factors that influence this ability center ion in the valence shell structure, charge, ionic radius, polarization effects etc.; the ligand and also by external conditions affect the microstructure of the complex to influence the stability of the complex. Key words: centrosome; metal ions; ligand; chelation effect 目 录 1 中心体的影响 ······················································································································1· 1.1 稀有气体型金属离子对配合物稳定性的影响 ·························································1· 10 1.2 d 型金属离子对配合物稳定性的影响 ····································································1· 1- 9 1.3 d 型金属离子对配合物稳定性的影响 ···································································2· 1.4 同一金属不同氧化态对配合物稳定性的影响 ··················