氯化溴合成溴化聚苯乙烯-化学工业与工程-天津大学.pdf

2010 3 27 2 M ar. 2010 CHEM ICAL INDUSTRY AND ENG INEERING Vol. 27 No. 2 : 1004- 9533( 2010) 02- 0144- 05 姚 颖, 张雨山, 蔡荣华, 张慧峰, 高书宝 ( , 300192) : 以氯化溴和聚苯乙烯为原料, 以三氯化锑为催化剂, 对合成阻燃剂溴化聚苯乙烯的工艺条件 进行了试验 究考察了催化剂添加量和反应温度对产物溴含量的影响, 并对合成的溴化聚苯乙 烯产品进行了溴含量白度(W b )红外光谱和热重等测试试验结果表明在催化剂添加量为 3% ~ 15% , 反应温度为 10~ 30 的条件下, 制备出的溴化聚苯乙烯产品溴含量大于 65%, 白度 (W b ) 大于 70热重分析表明制备的溴化聚苯乙烯具有较高的热稳定性在上述工艺条件下进行了公 斤级放大试验, 实现了实验流程的连续稳定操作, 验证了小试确定的工艺条件 : 氯化溴; 溴化聚苯乙烯; 阻燃剂; 放大试验 : TQ 2421 : A Synthesis of Brom inated Polystyrene with Brom ine Chloride YAO Y ing, ZHANG Yushan, CA I Ronghua, ZHANG Huifeng, GAO Shubao ( Institute ofT ianj in Seaw ater D esalination andM ultipurpose U tilization, State O ceanic Adm inistration, T ianjin 300192, China) Abstract: The optmi al parameters of synthesizing brom inated polystyrene ( BPS) w as determ ined in the presence of antmi ony chloride as a Lew is acid, brom ine chloride and polystyrene as raw m aterials. The effects of the amount of catalyst and reaction temperature in the synthesizing process on the brom ine con tent of product have been stud ied. Product qualities including brom ine content and wh iteness (W b ) have been exam ined. The results show thatw hen the amount of catalyst is 3% 15% and the reaction temper ature is 10 30 , the brom ine content could be above 65%, w hiteness (Wb ) cou ld be above 70. Ideal thermo stability and infrared spectrum w eremeasured. The resu lts of thermogravmi etric and FT IR analysis show that the products have ideal thermostab ility and h igh quality. In add ition, the optmi al synthesizing parameters