银修饰的二氧化钛多孔微管的制备表征及光催化活性Preparation.pdf

2007 年第65 卷 化 学 学 报 Vol. 65, 2007 第12 期, 1172～1176 ACTA CHIMICA SINICA No. 12, 1172～1176 ·研究简报· 银修饰的二氧化钛多孔微管的制备、表征及光催化活性 徐建华 戴维林* 李静霞 李 闻 曹 勇 范康年 (复旦大学化学系 上海市分子催化与创新材料重点实验室 上海 200433) 摘要 在冰乙酸存在条件下, 以四氯化钛水解法制备了具有锐钛矿晶型结构的二氧化钛多孔微管, 并用化学沉积法对 其进行修饰, 得到银修饰的二氧化钛多孔微管. 采用XRD, TG-DTA, SEM, TEM, XPS 及氮吸附等手段对其进行了表征. 氮吸附的结果显示该样品具有很高的比表面积, 银的修饰没有显著影响二氧化钛微管的孔结构; XRD 的表征结果显示, 银修饰的二氧化钛多孔微管具有良好的锐钛矿晶型; XPS 的分析结果表明银以游离的金属态存在; TEM 的观测结果显 示, 银团簇沉积于二氧化钛纳米晶粒的表面. 降解苯酚的光催化活性测试显示出银的修饰对二氧化钛的光催化活性有 显著的提高作用, 其中含银2.0% 的样品活性最高. 关键词 银; 修饰; 二氧化钛; 光催化; 苯酚 Preparation, Characterization and Photocatalytic Activity of Silver Modified Apertured TiO2 Microtubes XU, Jian-Hua DAI, Wei-Lin* LI, Jing-Xia LI, Wen CAO, Yong FAN, Kang-Nian (Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433) Abstract Apertured TiO microtubes have been fabricated by simple hydrolysis of titanium tetrachloride 2 using ammonia in the presence of glacial acetic acid. The microtubes were doped by silver using the chemical deposition method. The morphology and microstructure characteristics of the apertured silver doped TiO2 mi- crotubes were characterized by means of the X-ray powder diffraction (XRD), thermal analysis (TG-DTA), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectros- copy (XPS) and N2 absorption. The silver doped catalysts exhibit higher photocatalytic activity than