30万吨年煤制甲醇变换工段初步设计.docVIP

PAGE PAGE 41 摘 要 本设计是年产30万吨煤制甲醇项目一氧化碳变换工段的初步设计。煤制甲醇是目前我国战略转移的一个重要项目。针对我国多煤少油多煤少气的现状，国家提倡煤转油、煤转气和一系列化工项目。在煤转油和煤基甲醇等项目中，很重要的一个工段是CO变换。它的主要任务是调整C/H比，以满足后续的合成需求。本设计以煤制甲醇流程为工作基点，以非饱和塔型全低温耐硫不完全变换为讨论基础，采用山东齐鲁 科力化工研究院有限公司研发的牌号为QCS-03的钴钼系催化剂对来自煤直接气化的粗煤气进行CO变换。 设计的原则是技术先进、工艺成熟、经济合理、安全环保，在充分论证国内外各种先进生产方法、工艺流程和设备配置基础上，选用煤气化来的粗煤气进行CO变换，设计的内容包括生产工艺设计论证、工艺计算、设备设计选型及流程图、平面布置图、设备图的绘制；此外，在设计中充分考虑环境保护和劳动安全等非工艺部分。最后通过经济评估，本设计能够达到要求的经济效益。 关键词：煤制甲醇 CO 变换 碳氢比 Abstract This design is the annual output of 30 million tons of coal methanol carbon monoxide shift conversion section of the preliminary design. Coal to methanol is an important strategic shift in China project. More coal in our country less oil and more coal less gas status, national advocates of coal-oil, coal, gas transfer and a series of chemical projects. In the coal-oil and coal-based methanol project is a very important section in CO conversion. Its main task is to adjust the C / H ratio, the synthesis of the follow-up to meet demand. The design process for the work of coal methanol basis points, all non-saturated low-temperature sulfur-tolerant tower is not completely transformed into a basis for discussion, the use of force Chemical Research Institute Co., Ltd. Shandong Qilu Ke R D grades for the QCS-03 cobalt-molybdenum catalysts Gasification of coal directly from coal gas for CO conversion. Design principles are technologically advanced, mature technology, economical, safe environment, fully demonstrated at home and abroad in a variety of advanced production methods, process and device configuration based on the use of coal gasification to transform the crude gas to CO, the design includes production process design argument, process calculation, equipment selection and design of flow charts, floor plans, equipment, mapping; In addition, full consideration in the design of environmental protection and labor safety and other non-process part. Finally, economic evaluation, designed to meet the requirements of the econ