含氯漂白废水在厌氧过程中脱氯机理的研究.pdf

20 6 V ol. 20, No. 6 2000 11 ACTA SCIENT IAE CIRCUM STANT IAE Nov . , 2000 : 2000 : X131. 2 : A 陈元彩, 肖 锦, 詹怀宇, 王 杰 ( , 510640) : , GCMS , pH , . : ; ; Study on the dechlorination mechanism during anaerobic treatment of pulp bleachery effluent CHEN Yuancai, XAO in, ZHAN Huaiyu, WANG ie ( State Key Laboratory of Pulp Paper Engineering, South Ch ina University of T echnology, Guangzhou 510640) Abstr0act : Reductive dechlorination mechanisms was confirm ed through GCMS analysis during anaerobic treatment of pulp bleachery effluent. The influence of sulfide biologically produced and pH on the dechlorination revealed that nucleoph ilic substitution and alkaline hydrolysis w ere also nonbiological mechanism. Keywords: pulp bleachery effluents; anaerobic treatment ; dechlorination mechanism 50 , ( ) , , , , . , , . , 2000 0. 5 kg/ t( ) , 2005 0. 1 kg/ t( ) , British Columbia Ontario AOX . ( GB354492) AOX 1. 5 kg/ t( ) . [ 1- 2] . , , , , , , , . , , . 1 1. 1 : : : ( 99284) : ( 1967 ) , , ( ) 802 20 [ 3] CEH , . pH pHS- 3C ; ; CODCr ; [ 4] Schoniger AOX; : 0. 45 m , 752 CPPA ; Pellicon Casstte! , 0. 45 m , 1 kD , 1. 8 MPa; : H : HP5, : 70 KPa, He : 1 mL/ min , : 80∀ 5 min, 4∀ / min 290∀ , 30 min, : EI 50 eV, 1500 V , : 50550 amu, W ILEY . 1. 2 : , , 150 mL , , 100 mL , , , 3 g VSS/ L , pH 6. 8, . 2 2. 1 pH S2- AOX