低熔点低粘度的季铵盐类离子液体的合成与表征[论文设计].pdfVIP

( ) 46 2 Vol. 46, No. 2 JOURNAL OF NANJING U NIVERSITY 2010 3 Mar. 2010 ( NAT URA L SCIENCES) 肖 峰, 王冠楠, 吴有庭 , 方诚刚, 侯文龙, 张志炳 ( , , , , 210093) : , . , , , . - - - - - ( ( CF SO ) N ) ( PF ) ( BF ) ( H SO ) ( SCN ) 3 2 2 6 4 4 - (PTSA ) ; ; , . : , , , : O 621 Synthesis and characterization of novel quaternary ammonium ionic liquids with low melting point and viscosity X i ao F eng , Wang GuanN an, Wu YouT ing , Fang ChengGang , H ou We nL ong , Zhang Zh iB i ng ( Separation Engineering Research Center, Key Laboratory of Mesoscopic Chemistry of M inistry of Education of China, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing, 210093, China) Abstract: The length of the alkyl groups and the symmetry of t he cat ions in tetraalkylammoniumbased ionic liquids affect the physical propert ies and their applications. A novel class of ionic liquids based on triet hylbutylammonium cation was prepared in our group. In this series, ( CF SO ) N- [ bis 3 2 2 - - - - - ( trifluoromethanesufonyl) imide] , PF6 , BF4 , HSO4 , SCN a